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Reverse Spherification

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The Reverse Spherification technique consists of submerging a liquid with a mixture of calcium gluconate and calcium lactate in a bath of sodium alginate. There is also a variation of this technique, Frozen Reverse Spherification, that reduces preparation time, does not require practice and results in perfectly shaped spheres of consistent size.

Pros of Reverse Spherification

- Reverse Spherification is more versatile than Basic Spherification as it can make spheres with almost any product. It is best for liquids with high calcium content or alcohol content which makes them great for cocktails and dairy products like cheese, milk, cream and yoghurt.

- The resulting sphere is long-lasting and can be stored for Carbonated Mojito Spherelater consumption. Contrary to Basic Spherification, the process of jellification can be stopped when the sphere is removed from the sodium alginate bath and rinsed with water. This is very convenient when entertaining friends as you can prepare them ahead of time. This also allows you to macerate the spheres overnight to add some extra flavor (e.g. in aromatized olive oil or truffle water).

- Reverse Spherification results in a sphere with a thicker membrane than with Basic Spherification. Thanks to this, the resulting spheres can be manipulated easily, they conserve their shape better when plated (spheres produced with Basic Spherification flatten and acquire an orb or egg yolk shape when plated) and can be used in more ways (e.g. as fillings in sponge cakes or mousses).

- Jellification still occurs when the main ingredient liquid has some acidity. This is because in Reverse Spherification the jelling process occurs on the surface of the sphere as the sodium alginate fails to penetrate it. A translucent layer of gel is created around the main ingredient. In Basic Spherification, the gelling process occurs internally and has the color of the main ingredient.

- The main ingredient consistency and flavor is not altered by the addition of calcium gluconate and calcium lactate as they have no discernable flavor and dissolve in liquid without altering its density. This is the reason why in Reverse Spherification we don’t use calcium chloride which is very salty.

Cons of Reverse Spherification

- The thicker membrane of these spheres is more evident in your palate. You still get the “pop” sensation but in addition to the liquid you also feel the solid jelly in your mouth.

- The sodium alginate bath needs to rest for 12-24 hours before using it for Reverse Spherification to eliminate the air bubbles created by the process of dissolving the sodium alginate with the immersion blender.

- It is a little harder to get a perfect sphere on the plate with Reverse Spherification than with Basic Spherification. You are pouring the main ingredient into a viscous bath, the spheres tend to stick to each other if you don’t separate them in the bath and the thicker membrane maintains the shape better which is great if you were able to create a perfect sphere but not if your spheres are “deformed” (for optimal results read "10 Tips to Create a Perfect Sphere"). Frozen Reverse Spherification solves this problem if the main ingredient can be frozen. Learn about Frozen Spherification here.

- Reverse spherification is not great for making caviar as the main ingredient needs to be thickened to be able to penetrate the dense sodium alginate bath and cohere into a sphere. (for optimal results read "7 Tips for Making Spherification Caviar")

Preparing the Bath for Reverse Spherification

Blend the sodium alginate in 1/3 of water with an immersion blender until it is completely dissolved. Keep in mind that the sodium alginate is hard to dissolve in water and this process may take a few minutes. Then add the rest of the water and keep in the refrigerator for 12 to 24 hours to remove the air bubbles created by the blender.

Preparing the Main Ingredient for Reverse Spherification

Add the calcium gluconate and calcium lactate to 1/3 of the main ingredient to be used. Blend with an immersion blender until it is completely dissolved. Then add Xanthan to thicken the liquid and blend one more time. Increasing the density of the liquid helps form the spheres as the alginate bath is quite dense. Add the rest of the main ingredient and let it rest for 1 hour so that it loses part of the air created by the mixer.

Creating the Spheres

Now grab the syringe (if you are making caviar) or the measuring spoon of the desired size (if you are making ravioli, gnocchi, etc.) and carefully pour the preparation in the sodium alginate bath making sure the spheres don’t touch each other or they will stick. Wait for the time indicated in the recipe and carefully remove the sphere from the sodium alginate bath using a slotted spoon and rinse it in clean water.

I recommend you always start with one sphere first to adjust the pouring process and the time in the bath. If the sphere membrane is too subtle and the sphere easily breaks when handling it with the slotted spoon carefully or when plating it, extend the time in the sodium alginate bath until you get the desired strength. Keep in mind that the thinner the membrane the better experience people are going to have when eating it.

Consume the spheres or store them in a sealed container in the fridge. If you like, macerate them for a day in olive oil, truffle water or your favorite liquid.

Recommended Reading

Gettting Started with Spherification

Spherification recipes

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Spherification

  • http://bingobonusonline.se/gratis-bingo Estella Schweiker

    Pro post! This site I will bookmark for sure!

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  • Crundy 12

    Can you not reduce the amount of alginate in the bath to make it thinner in order to make caviar and leave the drops in for longer?

    • Anonymous

      Maybe but the problem is that the spheres will still stick to each other in the bath.

      • Crundy 12

        Hmm, what about using a large flat dish (like a lasagne dish) and spacing them out well? I agree it would take ages to do batches but at least they would store for longer.

        • Anonymous

          That may work but as you said, it will take for ages. If you try it, please let us know if it works!

  • Midnight__1

    so will an alginate bath keep indefinitely.?  i mean there should be no reason for it to go bad, I was thinking i could just keep sieving it to keep it clean and keep reusing it.

    • Anonymous

      The bath absorbs the flavors of the main ingredient so I wouldn’t reuse it many times with different ingredients. Not sure how long you can keep it but it may go bad after several days.

  • Vilson Vedana

    Awesome site. I mean, wow! I’m from Brazil and, although some top brazilian chefs (like Alex Atala) have been recently using some of MG’s techniques, it’s realy hard to get quality information an recipes around here.  I’ve discovered MG in 2009 and have been experimenting with it ever since. But only after finding your site I had the courage to invite some friends over and trying a proper “molecular dinner”. The result was an absolute success!

    After reading some of your other posts, I will now try to figure out some bold techniches (I’m specially interested in the soda siphon baloons using basic spherification, do you have some further information about that?), to experiment with some local ingredients (maybe heat-hydrated cassava starch baloon?) to open mhad some other ideas (have you ever thought about freezing the liquid prior to its “spherification”? with the use of silicone molds, this would allow to create not only spheres, but “cubes” or any other shape with liquids inside)

    I will give those ideas a try and let you know.

    • Anonymous

      Hi Vilson, glad you like the site!! Yes, freezing the main ingredient in silicon molds is a great way of getting different shapes with spherification and it also allows you to obtain them faster and with perfect shape. Share with us what happens after you experiment with these great ideas!
      Bests
      QC

  • Sara Villalon

    Getting ready formy first spherification!

  • tzak

    Very nice site, thank you for all the information! 

    I tried reverse spherification process to create strawberry raviolis, but the alginate bath I created was extremely thick (like a jelly). Although this seemed wrong, I was able made some raviolis, but with a very thick jelly outer-layer making them really not enjoyable to eat and a bit disgusting… like a jellyfish texture. ( I left them in the bath less than 2-3 min)I am guessing that the problem could be the water used for the algin bath (filtered tap water, with a basic home filter)… what do you think about it? …any ideas of other possible problems?

    Thanx!

    • QuantumChef

      Yes, the problem seems to be the water. A regular home filter usually removes most of the calcium content but it does not seem to be working in your case. Try with distilled water.

      • Brian

        Home water filters don’t completely remove calcium from water.  You would need to use a home reverse osmosis filtration system for that.  Old filters are especially bad at removing minerals from water.

  • Mansfield

    Is there any recipe to make caviar or spheres with “hard or jelly” outside and liquid inside that DONT become full jelly over time and a way to store them (perhaps some preserving agent) ? Please let me know. 

  • Rick

    Hello,

    How much sodium alginate do I use on for example 1 liter? Does at matter what the main ingredient is? 

    • QuantumChef

      5 g of sodium alginate for 1 liter of water and it would be the same for any recipe

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  • Bianca

    Hello! I was wondering…If I have Calcium Lactate and Calcium Gluconate, how much of each one do I need to mix to have the Calcium Lactate Gluconate ingredient? For example, if I need 6g, should I mix 3g each? Thanks!

    • QuantumChef

      No need to mix them. Just use half the quantity of calcium lactate to replace calcium lactate gluconate.

      • Bianca

        What is the calcium lactate % I should be using in recipes?

        • QuantumChef

          About 1.3%

  • Icemonkey

    I am searching for a way to make spherical Sherry, I figured reverse spherification because of the alcohol? Are there any recipes or steadfast ratios to go by?
    Thanks in advance!

  • Bob

    Hi, I am trying to find a way of making a roast pepper reverse spherifcation. Once i have made my puree of red peppers, around 200ml, I was wondering what quantites of the powders I would need? I have found many different recipes which has just resulted in confusion!
    I would be very grateful for your help! Thanks!

    • Bob

      Or maybe it would be better to do as spherification caviar instead??

    • QuantumChef

      Use 1% of calcium lactate gluconate by weight. The amount of Xanthan Gum depends on the consistency of your puree and you may not need any if it is thick enough. For liquids you usually need about 0.2% of Xanthan Gum.

      • Bob

        Brilliant, thank you!

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  • http://www.facebook.com/chayan.banerji Chayan Banerji

    “This is the reason why in Reverse Spherification we don’t use sodium chloride which is very salty…”
    …Is it a typo?..Do you mean sodium Citrate?

    • QuantumChef

      Yes, it is a typo…it should say calcium chloride. I’ll fix it, thanks!!

  • http://www.facebook.com/chayan.banerji Chayan Banerji

    Would it be easier to dissolve the sodium alginate if the solution were heated?
    …Some guidelines for the quantum of Xanthan to be added to the main body please :)

  • katriver

    i would like to caviar a sauce im serving with duck but due to times i can’t make them close to prepping the dish….is there a method to pre making and storing or even how they can hold their form for longer? My first attempt turned to jelly after a couple of hours and the flavour had become very watery as well…any tips would be awesome thank you :)

    • QuantumChef

      You can stop the gelification process by heating the caviar in a bath at 85 C (185 F) for 10 minutes. The bath needs to have the same density as the inside of the caviar so add xanthan gum and / or sugar to the water bath until you obtain similar viscocity. This is to prevent liquid leaking from the sphere into the bath. I hope this helps!

  • Ron

    Chef, I am trying to use reverse sphereication with Maple syrup. Maple syrup has 7% calcium per 100 grams. I was adding 1.2 g of calcium lactate to the syrup. It is not encapsulating right. My align bath is 1000ml water 200 g sugar 5 g algin. I do not want to thicken the syrup with xantham. The sphere is sinking to the bottom laying flat. Also the membrane is fragile seems like something is off and inconsistent. I tried to freeze but syrup doesn’t freeze that well. I tried to add xantham to my align bath so the syrup floated throughout the process. No luck.any suggestions on the recipe and how to keep the sphere floating?

    • QuantumChef

      Try stirring the bath so the sphere floats around rather than sit on the bottom. Are you dissolving the calcium lactate in water first? It may not be dissolving properly in the maple syrup. I hope this helps!

      • Ron

        Chef I am heating the the syrup up in the micro, until the lactate dissolves. Is there an issue with heating lacate up? Also I want to make a day in advance, I was told that if I make a solution with the same viscosity that it would stop the osmosis process? I made a sugar water and thickened it with xantham but was kinda of slimy. Maybe I could syrup thinned out with water to macerate in?

        • QuantumChef

          I think that may be the issue. The calcium lactate may not be hydrating and dispersing properly in the syrup given the lack of water. For the storing bath what you are suggesting is the best option: a syrup bath of the same density as the mix inside the sphere.